Mahamud Subir

Mahamud Subir

Associate Professor of Chemistry

Phone:765-285-8060

Room:CP 305


Postdoctoral Fellow McGill University (2012)
Columbia University Ph.D. (2009)
Columbia University M.Phil. (2008)
Columbia University M.A. (2005)
Queens College, CUNY B.A. (2003)

Related Link:
Subir Research Group

Research Interests

The aim of our research group is to elucidate chemistry that takes place in the atmosphere, environment and at nanoscale level from the perspective of surface science. Surfaces are everywhere, which split nature into phases. For instance, approximately two-third of the earth’s surface is air-water interface. The chemical processes that occur at the interfacial region are in general different from that of the bulk (i.e. gas or liquid phase) chemistry. Therefore, it is of fundamental interest to understand surface phenomena. Using surface selective nonlinear laser spectroscopy, along with traditional spectroscopic methods of UV-Vis, fluorescence, IR, and Raman, we investigate the influence of surfaces on chemical processes relevant to atmospheric, environmental and nano-science.

Selected Projects:

(1) Environmental Colloidal Surface Chemistry

Colloids (or suspended particles) are everywhere. Examples of colloids include atmospheric aerosols, emulsions, and metallic nanoparticles in the size range of 10–9 to 10–6 m. At this length scale, particles exhibit large surface area to volume ratio. Thus, chemistry at these surfaces can dominate. Of particular interest is the colloidal natural organic matter (NOM) present in the aquatic environment. The surface of colloidal NOM can play a role in aquatic pollutant distribution and transformation, but exactly how and to what extent remains unclear. Our research focus is to understand: (1) binding interactions of emerging contaminants with model NOM particles and (2) photochemical processes at the colloidal surfaces. Ultimately, the impact of the surface chemistry on the fate and transport of these pollutants and potential remediation techniques are elucidated.

 

Fig. 1 Generalized illustration of surface and heterogeneous chemistry pertaining to an aerosol particle

(2) Nanochemistry

Photovoltaic cells (PVCs) based on sensitized and hybrid nanoparticles are cost-effective and can potentially be highly efficient. Nanoparticles (NPs) provide a large surface area to volume ratio. Thus, molecular adsorption and surface chemistry play an important role in nanoparticle based solar cells. As a result, understanding the interfacial properties (Fig. 2) of NPs is of crucial importance. Our research focuses on surveying interfacial properties of an array of sensitized NPs applicable to the development of PVCs in a systematic way.

Fig. 2 Interfacial properties and chemical processes at NP surface

List of Publications

  1. Tyler Williams, Clare Walsh, Keith Murray, and Mahamud Subir*. Interactions of Emerging Contaminants with Model Colloidal Microplastics, C60 Fullerene, and Natural Organic Matter – Effect of Surface Functional Group and Adsorbate Properties. Environmental Science: Processes & Impacts. 2020, 22, 1190-1200.
  2. Daniel Headley, Ryan S. Young, Margaret Reece, and M. Subir*. Variation in Average Molecular Orientation of an Organic Anion at the Air-Aqueous Interface. Journal of Physical Chemistry C. 2018, 122 (9), 4945-4954.
  3. C. B. Nelson, T. Zubkov, J. D. Adair and M. Subir*. A Synergistic Combination of Local Tight Binding Theory and Second Harmonic Generation Elucidating Surface Properties of ZnO NanoparticlesPhysical Chemistry Chemical Physics2017, 19, 29991-29997.
  4. Tyler A. Williams, Jenny Lee, Cory A. Diemler, and M. Subir*. Magnetic vs. non-magnetic Colloids - A Comparative Adsorption Study to Quantify the Effect of Dye-Induced Aggregation on the Binding Affinity of an Organic Dye. Journal of Colloid and Interface Science2016, 481, 20-27. 
  5. P. A. Ariya*, M. Amyot, A. Dastoor, D. Deeds, A. Feinberg, G. Kos, A. Poulain, A. Ryjkov, K. Semeniuk, M. Subir and K. Toyota. Mercury Physicochemical and Biogeochemical Transformation in the Atmosphere and at Atmospheric Interfaces: A Review and Future DirectionsChemical Reviews2015, 115 (10), 3760-3802. Special Issue: 2015 Chemistry in Climate.
  6. M. Subir*, N. Eltouny, and P. A. Ariya*. A Surface Second Harmonic Generation Investigation of Volatile Organic Compound Adsorption on a Liquid Mercury Surface. RSC Advances. 2015, 119, 5, pp 2630 – 2636.
  7. C. B. Nelson, K. E. Shane, A. A. Al-Nossiff§, and M. Subir*. Optical Second Harmonic Generation from ZnO Nanofluids—A Tight Binding Approach in Determining Bulk χ(2).  J. Phys. Chem. C. 2015, 119 (5), pp 2630 – 2636. 
  8. M. Subir, P. A. Ariya*, and Dastoor, A. P. A Review of the Sources of Uncertainties in  Atmospheric Mercury Modeling II. Mercury Surface and Heterogeneous Chemistry – A Missing Link. Atmospheric Environment201146, 1-10.
  9. M. Subir, P. A. Ariya*, and Dastoor, A. P. A Review of the Sources of Uncertainties in Atmospheric Mercury Modeling I. Uncertainties in existing kinetic parameters – Fundamental Limitations and the Importance of Heterogeneous Chemistry. Atmospheric Environment2011, 45, 5664-5676.
  10. Rao, Y., Subir, M., McArthur E. A., Turro, N. J., and Eisenthal K. B.*, Organic Ions at the Air/Water Interface. Chemical Physics Letter2009477, 241-244.
  11. Subir, M., Liu, J., and Eisenthal, K. B.*, Protonation at the Aqueous Interface of Polymer Nanoparticles with Second Harmonic Generation.  J. Phys. Chem. C. 2008112, 15809-15812.
  12. Liu, J., Subir, M., Nguyen, K., and Eisenthal, K. B.*, Second Harmonic Studies of Ions Crossing Liposome Membranes in Real Time. J. Phys. Chem. B. 2008112, 15263-15266.

Course Schedule
Course No. Section Times Days Location
Physical Chemistry 1 444 11 1800 - 2050 W CP, room 412
Physical Chemistry 1 444 11 1300 - 1350 M CP, room 188
Physical Chemistry 1 444 11 1000 - 1050 M W F CP, room 188
Physical Chemistry 1 444 12 1700 - 1950 T CP, room 412
Physical Chemistry 1 444 12 1300 - 1350 M CP, room 188
Physical Chemistry 1 444 12 1000 - 1050 M W F CP, room 188
Exploration Select T 475 2 0000 - 0000
Research in Chemistr 670 1 0000 - 0000
Research in Chemistr 670 2 0000 - 0000