Ammonia Odor
We have
recently built a home and it has a strong ammonia odor. I attribute
it to either the cellulose or the sheetrock. The house is finished
and we have moved in. Should we have the air tested to make sure
that it is not harmful?-Bridget,
Arkansas
In new houses ammonia can be coming from either of two
places. Some latex paints when applied have high ammonia emissions.
Since ammonia is rapidly released and dissipated ammonia odors
associated with latex-based paints are fairly ephemeral, that is
that they go away relatively quickly (lets say in about a week)
Secondly many builders are increasingly using wet-spray applied
cellulose insulation in the side walls of new construction. In most
cases the manufacturers of this cellulose product use boric acid-polyborates
as both a fire retardant and mold inhibitor for the insulation.
Some manufacturers of this product use ammonia
sulfate and the ammonia can be emitted at both sensory and
chemically detectable levels. Reports of ammonia odors associated
with wet spray applied cellulose insulation (WSACI) are not uncommon
in southern states. Unlike ammonia emissions from latex-based paints
ammonia odors associated with WSACI can persistent for months or
longer since the ammonia is formed from the decomposition of
ammonium sulfate as environmental conditions for such decomposition
become favorable.
Documentation of this problem was been done by Barb Epstein,
Industrial Hygienist( ...formerly with
Air Quality Sciences, currently with Epstien Environmental
Resources...
) on investigating odor complaints in two recently
constructed single-family residences in a southeast metropolitan
area. In both case the buildings were WSACI insulated.
The
investigation involved an on-site visual and sensory inspection as
well as air testing in both building spaces and wall cavities. In
the inspection ammonia odors were noted to be present in both houses
varying in intensity in one house from slight to-moderate and in
the second house from moderate-to-strong. The ammonia odor was
stronger on lower as compared to upper house levels. In a second
visit the odor was less intense in one house but was moderate to
strong in the other.
In the
first residence 8 air samples were collected in living spaces and 10
in wall cavities. Living space and wall cavity concentrations
averaged ~ 2.0 and 6.6 ppmv respectively. All living space
concentrations exceeded the odor threshold of ~ 1.3 ppmv. As
expected the wall cavity concentrations were significantly higher
than air concentrations indicating that the wall cavities were the
source of the ammonia in building spaces and that WSACI was
potentially the source of ammonia.
In the
second residence 5 samples of room and cavity air were collected
with average concentrations of 3.9 and 20 ppmv respectively. This
house was determined to have a moderate to strong odor in an
initial, and follow-up inspections.
A second
round of testing in the first house was conducted with average
concentration of 0.80 ppmv suggested that the concentration
decreased with time. The contractor after applying whole house
dehumidification subsequently reported that the ammonia odor
decreased to acceptable levels and these houses were then occupied
by those who had purchased them.
You have asked
whether the air in your house should be tested to make sure that it
is not harmful. My response to your question can not be simply
stated.
Though
there are occupational exposure guidelines for ammonia (25 ppmv
8-hour average TLV) these can not be applied to residential settings
to protect building occupants. Some scientists have suggested that
an appropriate indoor residential guideline exposure level be set at
1/10 the TLV. That would be 2.5 ppmv which is above the odor
threshold. Another approach is the use of sensory irritation data
derived from laboratory animal testing (RD 50 values) multiplied by
1/1000. Using this approach the acceptable residential exposure
concentration for ammonia would be 0.3 ppmv.
As I have
previously written in postings on this website the primary health
concern associated with WSACI is its propensity to allow a
significant quantity of mold to grow on and in it and for this mold
to significantly increase living space mold concentrations (and in
so doing result in significant increases in human exposure). So in
advising you or others relative to the conduct of air testing I
would recommend that one also test airborne mold levels using both
spore trap and culturable mold techniques and to also have a bulk
sample of the WCSACI tested for mold types and concentrations by
QPCR(a DNA test).
August 9, 2007